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Preheat your oven to 400°F. Generously butter and lightly flour four 6-ounce ramekins. Place the prepared ramekins on a baking sheet.
In a heatproof bowl set over a saucepan of simmering water (creating a double boiler), melt the chopped semisweet chocolate and unsalted butter together, stirring frequently until smooth. Alternatively, melt in a microwave-safe bowl in 30-second intervals, stirring after each. Remove from heat and let the mixture cool slightly.
In a large mixing bowl, whisk together the granulated sugar, large eggs, and large egg yolks until the mixture is light in color and slightly thickened, which should take about 2 to 3 minutes.
Gradually whisk the slightly cooled melted chocolate and butter mixture into the egg mixture until they are well combined and smooth.
Sift the all-purpose flour and unsweetened cocoa powder over the chocolate mixture. Gently fold with a rubber spatula until just combined. Be careful not to overmix, as this can lead to a tough cake.
Divide the batter evenly among the four prepared ramekins. Place 1 tablespoon of hazelnut spread directly into the center of the batter in each ramekin, gently pushing it down slightly.
Bake for 12 to 14 minutes, or until the edges of the cakes are set but the centers are still noticeably jiggly when gently shaken. This indicates the molten center.
Carefully remove the ramekins from the oven. Let them cool for just 1 minute on the baking sheet. Then, carefully invert each cake onto a serving plate. Dust generously with confectioners' sugar before serving immediately.

Preheat your oven to 400°F. Generously butter and lightly flour four 6-ounce ramekins. Place the prepared ramekins on a baking sheet.
In a heatproof bowl set over a saucepan of simmering water (creating a double boiler), melt the chopped semisweet chocolate and unsalted butter together, stirring frequently until smooth. Alternatively, melt in a microwave-safe bowl in 30-second intervals, stirring after each. Remove from heat and let the mixture cool slightly.
In a large mixing bowl, whisk together the granulated sugar, large eggs, and large egg yolks until the mixture is light in color and slightly thickened, which should take about 2 to 3 minutes.
Gradually whisk the slightly cooled melted chocolate and butter mixture into the egg mixture until they are well combined and smooth.
Sift the all-purpose flour and unsweetened cocoa powder over the chocolate mixture. Gently fold with a rubber spatula until just combined. Be careful not to overmix, as this can lead to a tough cake.
Divide the batter evenly among the four prepared ramekins. Place 1 tablespoon of hazelnut spread directly into the center of the batter in each ramekin, gently pushing it down slightly.
Bake for 12 to 14 minutes, or until the edges of the cakes are set but the centers are still noticeably jiggly when gently shaken. This indicates the molten center.
Carefully remove the ramekins from the oven. Let them cool for just 1 minute on the baking sheet. Then, carefully invert each cake onto a serving plate. Dust generously with confectioners' sugar before serving immediately.